Karbon trioksida
Karbon trioksida (CO3) merupakan sebuah produk reaksi tidak stabil dari reaksi antara karbon dioksida (CO2) dengan oksigen atomik (O).[1] Ia berbeda dengan ion karbonat (CO32−). Ia juga telah terdeteksi pada reaksi antara karbon monoksida dengan oksigen O2. Ia juga ditemukan pada zona hanyutan lucutan korona negatif.[2] Karbon trioksida dapat dibuat dari penghembusan ozon pada es kering.
Terdapat tiga bentuk isomer karbon trioksida, ditandai dengan Cs, D3h, dan C2v. Telah ditunjukkan keadaan C2v merupakan keadaan dasar molekul. Diarsipkan 2012-06-30 di Archive.is
Referensi
- Sabin, J. R.; Kim, H. (1971). "A theoretical study of the structure and properties of carbon trioxide". Chemical Physics Letters. 11 (5,): 593–597. doi:10.1016/0009-2614(71)87010-0.
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- Electronic structure and spectroscopy of carbon trioxide Diarsipkan 2012-06-30 di Archive.is
- Sabin J. R., Kim H. (1971). "A theoretical study of the structure and properties of carbon trioxide". Chemical Physics Letters. 11 (5): 593–597. doi:10.1016/0009-2614(71)87010-0.
- Sobek V., Skalný J. D. (1993). "A simple model of processes in the drift region of negative corona discharge in a mixture of air with halocarbons". Czechoslovak Journal of Physics. 43 (8): 807. doi:10.1007/BF01589802.
- Pople J. A. , Seeger U., Seeger R., Schleyer P. v. R. (2004). "The structure of carbonate". Journal of Computational Chemistry. 1 (2): 199–203. doi:10.1002/jcc.540010215.
- Moll N. G., Clutter D. R., Thompson W. E. (1966). "Carbonate: Its Production, Infrared Spectrum, and Structure Studied in a Matrix of Solid CO2". The Journal of Chemical Physics. 45 (12): 4469–4481. doi:10.1063/1.1727526.
- Gimarc B. M., Chou T. S. (1968). "Geometry and Electronic Structure of Carbon Trioxide". The Journal of Chemical Physics. 49 (9): 4043–4047. doi:10.1063/1.1670715.
- DeMore W. B., Jacobsen C. W. (1969). "Formation of carbon trioxide in the photolysis of ozone in liquid carbon dioxide". Journal of Physical Chemistry. 73 (9): 2935–2938. doi:10.1021/j100843a026.
- DeMore W. B., Dede C. (1970). "Pressure dependence of carbon trioxide formation in the gas-phase reaction of O(1D) with carbon dioxide". Journal of Physical Chemistry. 74 (13): 2621–2625. doi:10.1021/j100707a006.
- Francisco J. S., Williams I. H. (1985). "A theoretical study of the force field for carbon trioxide". Chemical Physics. 95 (3): 373. doi:10.1016/0301-0104(85)80160-9.
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